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Abstract

For a long time， with the continuous expansion of the oil and gas genesis theory and the increasing global demand for clean energy， hydrogen， as an important link connecting the theory of inorganic and organic hydrocarbon generation， as well as a promising clean energy， has gradually attracted widespread academic attention. The genesis of hydrogen in natural gas is relatively complex and diverse. According to its reaction mechanism， it can be divided into two categories： inorganic and organic. Inorganic genesis is mainly earth degassing， water rock reaction and water radiation decomposition， while organic genesis is dominated by biological action and organic matter pyrolysis. At present， hydrogen isotope and geochemical characteristics of associated gases are mainly used to identify the origin of hydrogen. However， due to the complex and diverse sources of hydrogen and its active chemical properties， it is still unable to identify the origin of hydrogen systematically and accurately. Due to the extensive genesis of hydrogen， natural gas with different hydrogen concentrations has been found in different geological conditions around the world， and the hydrogen content varies greatly （0.1%-99%）. Hydrogen can participate in hydrocarbon generation in Fischer Tropsch synthesis as a reducing agent， and also can be used as a hydrogen source to improve the hydrocarbon yield during the thermal evolution of organic matter. Therefore， the existence of hydrogen may extend the lower limit of deep gas exploration and development. Based on the systematic summary of the genetic mechanism and distribution of hydrogen， this paper discusses the energy significance of hydrogen in natural gas， and provides a reference for the future research on hydrogen rich natural gas resources.