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Journal Article

Polymorphism and orientation control of copper-dicarboxylate metal–organic framework thin films through vapour- and liquid-phase growth

Authors

Rubio-Giménez,  Víctor
External Organizations;

Carraro,  Francesco
External Organizations;

Hofer,  Sebastian
External Organizations;

Fratschko,  Mario
External Organizations;

/persons/resource/stassin

Stassin,  Timothée       
1.4 Remote Sensing, 1.0 Geodesy, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

Rodríguez-Hermida,  Sabina
External Organizations;

Schrode,  Benedikt
External Organizations;

Barba,  Luisa
External Organizations;

Resel,  Roland
External Organizations;

Falcaro,  Paolo
External Organizations;

Ameloot,  Rob
External Organizations;

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Citation

Rubio-Giménez, V., Carraro, F., Hofer, S., Fratschko, M., Stassin, T., Rodríguez-Hermida, S., Schrode, B., Barba, L., Resel, R., Falcaro, P., Ameloot, R. (2024): Polymorphism and orientation control of copper-dicarboxylate metal–organic framework thin films through vapour- and liquid-phase growth. - CrystEngComm, 26, 8, 1071-1076.
https://doi.org/10.1039/D3CE01296D


Cite as: https://gfzpublic.gfz.de/pubman/item/item_5025700
Abstract
Precise control over the crystalline phase and crystallographic orientation within thin films of metal–organic frameworks (MOFs) is highly desirable. Here, we report a comparison of the liquid- and vapour-phase film deposition of two copper-dicarboxylate MOFs starting from an oriented metal hydroxide precursor. X-ray diffraction revealed that the vapour- or liquid-phase reaction of the linker with this precursor results in different crystalline phases, morphologies, and orientations. Pole figure analysis showed that solution-based growth of the MOFs follows the axial texture of the metal hydroxide precursor, resulting in heteroepitaxy. In contrast, the vapour-phase method results in non-epitaxial growth with uniplanar texture only.